Methanol, also known as "wood alcohol", is an organic compound and the simplest saturated monohydric alcohol. It is a colorless, transparent, flammable, volatile toxic liquid. Ingestion of 5 to 10 ml can cause blindness, and drinking a large amount can lead to death. Methanol is non-corrosive to metals at room temperature (except lead and aluminum) and has a slight alcohol smell. Relative density 0.792 (20/4℃), melting point -97.8℃, boiling point 64.5℃, flash point 12.22℃, autoignition point 463.89℃, vapor density 1.11, vapor pressure 13.33KPa (100mmHg21.2℃), vapor and air mixture explosion limit 6 to 36.5% (volume ratio), miscible with water, ethanol, ether, benzene, ketones, halogenated hydrocarbons and many other organic solvents. It is usually used as a solvent, antifreeze, fuel or neutralizer.
Chemical Properties
| Property | Value |
Melting point | -98 °C(lit.) |
Boiling point | 65.4 °C(lit.) |
Density | 0.791 g/mL at 25 °C |
Vapor density | 1.11 (vs air) |
Vapor pressure | 410 mm Hg ( 50 °C) |
Refractive index | n20/D 1.329(lit.) |
Fp | 52 °F |
Storage temp. | 2-8°C |
Solubility | Benzene: miscible(lit.) |
Pka | 15.2(at 25℃) |
Form | Liquid Free From Particulates |
Color | <10(APHA) |
Specific Gravity | 0.793 (20/20℃) |
Relative polarity | 0.762 |
Odor | Faint alcohol odor detectable at 4 to 6000 ppm (mean = 160 ppm) |
Explosive limit | 5.5-44%(V) |
Odor Threshold | 33ppm |
Water Solubility | miscible |
λmax | λ: 210 nm Amax: 0.50λ: 220 nm Amax: 0.30λ: 230 nm Amax: 0.15λ: 235 nm Amax: 0.10λ: 240 nm Amax: 0.05λ: 260 nm Amax: 0.01λ: 400 nm Amax: 0.01 |
Merck | 14,5957 |
BRN | 1098229 |
Henry's Law Constant | 4.99 at 25 °C (headspace-GC, Gupta et al., 2000) |
Exposure limits | TLV-TWA (200 ppm) (ACGIH), 260mg/m3, 1040mg/m3 (800 ppm) 15minutes (NIOSH); STEL 310mg/m3 (250 ppm); IDLH 25,000 ppm (NIOSH). |
Dielectric constant | 33.6(20℃) |
LogP | -0.770 |
CAS DataBase Reference | 67-56-1(CAS DataBase Reference) |
NIST Chemistry Reference | Methyl alcohol(67-56-1) |
EPA Substance Registry System | Methanol (67-56-1) |
Safety Information
| Property | Value |
Hazard Codes | Xn,T,F |
Risk Statements | 10-20/ 21/ 22-68/ 20/ 21/ 22-39/ 23/ 24/ 25-23/ 24/ 25-11-40-36-36/ 38-23/ 25 |
Safety Statements | 36/ 37-7-45-16-24/ 25-23-24-26 |
RIDADR | UN 1170 3/PG 2 |
WGK Germany | 1 |
RTECS | PC1400000 |
F | 3-10 |
Autoignition Temperature | 385 °C |
TSCA | Yes |
HS Code | 2905 11 00 |
HazardClass | 3 |
PackingGroup | II |
Hazardous Substances Data | 67-56-1(Hazardous Substances Data) |
Toxicity | LD50 oral (rat)5628 mg/kgLD50 skin (rabbit)15,840 mg/kgLC50 inhal (rat)>145,000 ppm (1 h)PEL (OSHA)200 ppm (260 mg/m3)TLV-TWA (ACGIH)200 ppm (260 mg/m3)—skinSTEL (ACGIH)250 ppm (328 mg/m3) |
IDLA | 6,000 ppm |
Product Usage
Methanol, often referred to as wood alcohol, is a fundamental building block in the global chemical industry. Its most significant application is as a feedstock for producing formaldehyde, acetic acid, and various plastics, fibers, and resins. In the energy sector, methanol is gaining prominence as a clean-burning fuel or fuel additive, contributing to reduced emissions in marine and automotive transport. Furthermore, it serves as a high-performance industrial solvent for paints, varnishes, and inks, and is essential in wastewater treatment as a carbon source for denitrification.